The weak vibration selleck resonance centered at 2,090 cm−1 can be assigned to the coupled H-Si-Si-H stretching

or monohydride Si-H bonds. This result shows that the Si-H bonds were only partially replaced by Si-C because of the rigid and steric effect of the N-vinylcarbazole molecule. Compared to the IR spectrum of N-vinylcarbazole, similar vibrational peaks can be found in the spectrum of N-ec-Si QDs. The CH2 symmetric and asymmetric stretching vibrations in the range 2,920 to 2,850 cm−1, the CH2 bending vibration at approximately 1,450 cm−1, and the aromatic group vibration bands at approximately 750 cm−1 can be assigned to the surface-modified N-ethylcarbazole (-NC14H12) ligands. This indicates the successful modification of N-vinylcarbazole onto the Si QDs. It should be noticed that the Si-O-Si vibration band at 1,000 to 1,200 cm−1 is recorded, suggesting possible oxidation of the Si QD surface. This may due to the steric effect of carbazole, that is, the Si QD surface cannot be fully protected by the ligand, in which some Si-H remained and encountered oxidation when exposed to air. TH-302 manufacturer Figure 2 Characterization of

Si QDs and N-ec-Si QDs. (a) XRD pattern of the hydrogen-terminated Si QDs. (b) TEM image and HRTEM image (inset) of the N-ec-Si QDs (scale bar 20 nm, inset 2 nm). (c) Size distribution of the N-ec-Si QDs. (d) FTIR spectra of the N-ec-Si QDs and pure N-vinylcarbazole. Figure 3a shows the absorption spectra of N-vinylcarbazole and N-ec-Si QDs. The absorption band at 320 to 360 nm of the N-ec-Si QDs is assigned Buparlisib clinical trial to the carbazole ligand. It suggests that ligands can be employed to enhance the absorption of pure Si QDs, therefore providing a potential strategy to increase the light-harvesting efficiency of QDs clonidine in solar cells [52, 53]. Upon excitation at 302 nm, the N-ec-Si QDs and N-vinylcarbazole show intense emission bands at approximately 358 nm and

approximately 366 nm, respectively (Figure 3b). In comparison with N-vinylcarbazole, the emission in the 9-ea-Si QDs exhibits a blueshift of 8 nm and a shoulder peak at approximately 372. When carbazole was linked to the surface of Si QDs by Si-C bond by the hydrosilylation reaction, the vinyl group in N-vinylcarbazole was transformed into an ethyl group. Therefore, the conjugate system of the molecule reduced from N-vinylcarbazole to carbazole, inducing a bigger electronic bandgap. In addition, the ligand to QD bonding would enhance the structural rigidity of the ligand. These reasons may contribute to the blueshift of the PL spectrum. Commonly, the extension of molecular conjugated orbitals of a ligand to the attached materials would lead to a redshift. In N-ec-Si QDs, the ethyl group formed through the hydrosilylation reaction separates the conjugated part, the carbazole group, from the silicon nanocrystal, which prevents or weakens the interaction of the carbazole group with the electronic wave functions of the Si QDs.